Mass Transfer - Video Lectures
Topic outline
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Announcements Forum
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Transfer of Solute from Gas to Liquid - Two-film Theory Page
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Controlling Resistance from Individual Mass Transfer Coefficients Page2000-2-14-mtThe individual mass transfer coefficients (mol/m2.s) for absorption of a solute from a gas mixture into a liquid solvent are \(k_x\) =4.5 and \(k_y\) = 1.5. The slope of the equilibrium line is 3. Which of the following resistance(s) is (are) controlling?
- liquid-side
- gas-side
- interfacial
- both liquid and gas side
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2017-16-mtConsider steady state mass transfer of a solute \(A\) from a gas phase to a liquid phase. The gas phase bulk and interface mole fractions are \(y_{A,G}\) and \(y_{A,i}\), respectively. The liquid phase bulk and interface mole fractions are \(x_{A,L}\) and \(x_{A,i}\), respectively. The ratio \(\dfrac {(x_{A,i}-x_{A,L})}{(y_{A,G}-y_{A,i})}\) is very close to zero. This implies that mass transfer resistance is
- negligible in the gas phase only
- negligible in the liquid phase only
- negligible in both the phases
- considerable in both the phases
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Absorption of Solute where Ky=ky Page1990-5-i-mtIn the absorption of a solute gas from a mixture containing inerts in a solvent, it has been found that the overall gas transfer coefficient is nearly equal to the individual gas film transfer coefficient. It may therefore be concluded that:
- the process is liquid film controlled
- the gas is sparingly soluble in the solvent
- the transfer rate can be increased substantially by reducing the thickness of the liquid film
- the transfer rate can be increased substantially by reducing the thickness of the gas film
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Resistance for Solute with Less Solubility in Liquid Page1998-1-17-mtIn an interphase mass transfer process, the lesser the solubility of a given solute in a liquid, the higher are the chances that the transfer process will be
- liquid phase resistance controlled
- gas phase resistance controlled
- impossible
- driven by a nonlinear driving force
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Conditions for Absorption to become Gas-film Controlled Page2012-18-mtFor which of the following operations, does the absorption operation become gas-film controlled?
- [P.] The solubility of gas in the liquid is very high
- [Q.] The solubility of gas in the liquid is very low
- [R.] The liquid-side mass transfer coefficient is much higher than the gas-side mass transfer coefficient
- [S.] The liquid-side mass transfer coefficient is much lower than the gas-side mass transfer coefficient
- P & Q
- P & R
- P & S
- Q & R
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Controlling Resistance for Absorption of CO2 in Amine Page2014-19-mtAssuming the mass transfer coefficients in the gas and the liquid phases are comparable, the absorption of CO2 from reformer gas (CO2+H2) into an aqueous solution of diethanolamine is controlled by
- gas phase resistance
- liquid phase resistance
- both gas and liquid phase resistances
- composition of the reformer gas
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Absorption of H2S in Amine - Controlling Resistance Page
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Absorption of Sparingly Soluble Gas in Liquid Page
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Gas-film Thickness from Diffusion Rate and Interface Concentration Page1991-6-i-mtThe diffusion rate of ammonia from an aq.solution to the gas phase is \(10^{-3}\) kmol/m\(^2\).s. The interface equilibrium pressure of \(\ce {NH3}\) is 660 N/m\(^2\) and the concentration of \(\ce {NH3}\) in the gas phase is 5%. If the total pressure is 101 N/m\(^2\), temperature is 295 K and diffusivity of \(\ce {NH3}\) is 0.24 cm\(^2\)/s, the gas film thickness is ____________(\(\mu \)m).
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Concentration Profile for Absorption of Solute Page
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Molar Flux and Interfacial Concentration Page1990-15-iii-mtConsider a system in which component \(A\) is being transferred from a gas phase to a liquid phase. The equilibrium relation is given by \(y_A = 0.75 x_A\) where \(y_A\) and \(x_A\) are mole fractions of \(A\) in gas and liquid phase respectively. At one point in the equipment, the gas contains 10 mole % \(A\) and liquid 2 mole % \(A\). Gas film mass transfer coefficient \(k_y\) at this point is 10 kmol/(h.m\(^2\).\(\Delta y_A\)) and 60% of the resistance is in the gas film. Calculate:
- the overall mass transfer coefficient in kmol/(h.m\(^2\).\(\Delta y_A\))
- mass flux of \(A\) in kmol/(h.m\(^2\))
- the interfacial gas concentration of \(A\) in mole fraction
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Colburn j-factor of Mass Transfer Page
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Mass Transfer Correlation in terms of jD Factor Page
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Reynolds Analogy - Applicability Page
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Correlation for Heat Transfer from that of Mass Transfer Page
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Time for Complete Sublimation Page2019-50-mtTwo spherical camphor particles of radii 20 cm and 5 cm, far away from each other, are undergoing sublimation in a stream of air. The mass transfer coefficient is proportional to \(1/\sqrt {r(t)}\), where \(r(t)\) is the radius of the sphere at time \(t\). Assume that the partial pressure of camphor far away from the surface of the particle is zero. Also, assume quasi-steady state, identical ambient conditions, and negligible heat effects. If \(t_1\) and \(t_2\) are the times required for complete sublimation of the 20 cm and 5 cm camphor particles, respectively, the ratio \(t_1/t_2\) is ________ .
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Unsteady Dissolution of Solute Page
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Rate of Dissolution from Mass Transfer Coefficient Page
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Significances of Prandtl Number and Schmidt Number Page
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Sherwood Number for Diffusion of Water in Air Page
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Interfacial Area from Hold-up Data Page