41 - Radiation
8. Radiative Properties of Materials
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For most solids, the transmissivity is zero, and thus they may be called opaque to thermal radiation. For an opaque body, \(\rho + \alpha = 1\).
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A black body is one for which \(\alpha = 1\). A black body neither reflects nor transmits any thermal radiation.
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Kirchhoff’s law: it is a relation between absorptivity and emissivity at a given wavelength (\(\lambda\)) as given below: \[{\varepsilon_\lambda = \alpha_\lambda}\]
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A gray body is defined as one which has a constant value of emissivity, so that for any temperature range, it radiates the same proportion of energy radiated by a black body. Similarly it will have a constant absorptivity. With the application of Kirchhoff’s law, for gray body \(\varepsilon = \alpha\).
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A black body absorbs all incoming radiation and emits the maximum possible, \(\alpha = \varepsilon = 1\); where \(\varepsilon\) is emissivity.
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Since we see reflected light (radiation), a so-called black body will appear black, no light being reflected from it. A small hole in a large cavity closely approaches a black body. Radiation incident to the hole has very little opportunity to be reflected back out of the hole.
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Highly polished and white surfaces generally have lower emissivities than rough or black surfaces.