Topic outline

  • General

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    • Course Summary: Show more...
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    • Announcements Forum
    • Online Calculator for GATE URL
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    • Overview of GATE Chemical Engineering Page
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    • Details of Classes Database

  • Theory

    • Theory - Part 1 Page
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    • Basic Concepts - slides Page
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    • PVT Behavior of Pure Components - slides Page
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    • First Law - slides Page
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    • Theory - Part 2 Page
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    • Second Law - slides Page
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    • Thermodynamic Relations - slides Page
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    • Theory - Part 3 - Flow Processes Page
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    • Slides Page
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    • Theory - Part 4 - Solution Thermodynamics Page
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    • Slides Page
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    • Theory - Part 5 - Phase Equilibria and Reaction Equilibria Page
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    • Slides Page
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  • Basic Concepts - Problems

    • Mass of Piston for a given Pressure of Cylinder Page
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    • New Temperature Scale Page

      Class-0 on 05-May-2023

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    • Change in Pressure for a Given Change in Temperature Page
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    • Representing Work in PV Diagram Page
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    • Work of Constant Pressure Expansion of Air Page
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    • Work in Melting of Ice Page
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    • Processes in Piston-Cylinder System Page
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    • Temperature of System for Movement of Piston Page
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    • Heating of a Gas Confined in a Piston-Cylinder Arrangement Page
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    • Heating of Contents in a Rigid Vessel Page
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    • Temperature Change due to Expansion of an Ideal Gas Page
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    • Work done by a Gas against Constant Resisting Pressure Page
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    • Work done by a Gas Expanding in an Evacuated Space Page
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    • Quiz - Basic Concepts - Conceptual Questions
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    • Quiz - Basic Concepts - Numerical Questions
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  • PVT Behavior - Problems

    • Density of Ideal Gas Page
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    • Pressure of Ideal Gas Mixture Page
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    • Pressure of Connected Reactors Page
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    • Mass of Gas in a Pressure Vessel Page
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    • Pressure from van der Waals Equation Page
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    • Compressibility Factor Page
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    • Compressibility Factor from van der Waals Equation Page
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    • Volume from Compressibility Factor Page
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    • Work for Isothermal Compression of Liquids Page
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    • Volume from Virial Gas Equation - Newton-Raphson Method Page
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    • Compressibility Factor from Corresponding State Principle Page
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    • Quiz - PVT Behavior - Conceptual Questions
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    • Quiz - PVT Behavior - Numerical Questions
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  • First Law - Problems

    • CheckList-FirstLaw
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    • Relation for Heat Gain Page
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    • Heat Transfer to Piston-Cylinder System Page
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    • Heat Work Interactions of Cyclic Process Page
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    • Heat Flow Estimation from PV Diagram Page
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    • Work done by Turbine Page
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    • Specific Heat of Ideal Gas Page
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    • Heat and Work Interactions of Closed System Page
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    • Energy Interactions of Closed System Page
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    • Heat Transfer to a Closed System Page
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    • Electrical Heating of Closed System Page
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    • Heat and Work Interactions of a Cyclic Process Page
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    • Additional Problems
    • Irreversible Compression Page
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    • Work of Turbine Page
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    • First Law - Conceptual Quiz
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    • First Law Quiz - Numerical Questions - Set1
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    • First Law Quiz - Numerical Questions - Set2
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  • Second Law - Problems

    • Power from Unloading of LNG Page
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    • Carnot Refrigerator Driven by Carnot Engine Page
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    • Entropy Change for Heat Transfer Page
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    • Entropy Change for Irreversible Compression of Ideal Gas Page
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    • Efficiency of a Thermodynamic Cycle Page
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  • Thermodynamic Relations - Problems

    • Partial Derivatives of PVT Page
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    • Slope of Solid-Liquid Coexistence Line Page
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    • Slope of Mollier Diagram Page
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    • Latent Heat from Vapor Pressure Data Page
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    • Isothermal Compression of Water Page
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    • Thermodynamic Property Changes for Non-ideal Gas Page
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  • Flow Processes - Problems

    • Cyclic Relation for P-T-H Page
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    • Joule-Thomson Coefficient from PVT Page
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    • Power from a Turbine Page
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    • Filling of Gas to a Tank Page
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    • Additional Problems
    • Vapor Compression Refrigeration Page
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  • Solution Thermodynamics - Problems

    • Volume Change of Mixing Page
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    • Partial Molar Enthalpy at Infinite Dilution Page
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    • Fugacity from G Page
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    • G/RT of Solution Page
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    • Activity Coefficient and Excess Gibbs Free Energy Page
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    • Slope of lnGamma vs Composition Curve Page
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  • Phase Equilibria - Problems

    • Bubble Composition from P, T, Vapor Pressure Data Page
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    • Pressure Range for Two-phase at Constant Temperature Page
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    • Excess Gibbs Free Energy from VLE Data Page
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    • VLE of Non-ideal Solution from Azeotropic Data Page
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    • VLE from Azeotropic Composition Page
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    • Henry's Law for Solute and Raoult's Law for Solvent Page
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    • Flash Calculation Page
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  • Reaction Equilibria - Problems

    • Relation between Equilibrium Constant and Extent of Reaction Page
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    • Mole Balance in Multiple Reaction System Page
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    • Equilibrium Composition and Conversion Page
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    • Equilibrium Composition with Non-ideal Solution Page
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      Additional Problems

    • Equilibrium Composition from Heat of Formation, Free Energy Change of Formation, Specific Heat Data Page
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    • Equilibrium Composition of Multiple Reaction Equilibria Page
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    • Equilibrium Conversion of Ammonia Page
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  • Review - Conceptual Questions

    • Basic Concepts
    • Work of Free Expansion Page
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    • Temperature Change of Ideal Gas due to Expansion Page
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    • Heating of Tank Contents Page
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    • PVT Behavior of Pure Components
    • Solid to Vapor Transformation Page
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    • Ideal Gas - Pressure Temperature Conditions Page
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    • Conditions at Critical Point Page
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    • Parameters of vander Waals Equation Page
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    • Compressibility Factor of Water Vapor Page
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    • Compressibility Factor at Critical Point Page
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    • Compressibility Factor from P, T, Pc, Tc Data Page
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    • First Law
    • Q, W, U of Processes Page
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    • Enthalpy Change of Ideal Gas Page
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    • Work of Adiabatic Process Page
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    • PV Curve of Isothermal and Adiabatic Processes Page
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    • Heat Input at Constant Pressure Page
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    • Flow of Air for a Given Power Output of Turbine Page
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    • Second Law
    • Violation of Thermodynamic Laws Page
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    • Thermodynamic Possibilities Page
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    • Maximum Work of Heat Engine Page
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    • Isothermal Expansion of Ideal Gas Page
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    • Entropy Change of Cyclic Process Page
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    • Reversible Heat Transfer Page
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    • Internal Energy and Entropy Changes for Cooling Process Page
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    • Total Entropy Change for Heating of Water Page
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    • Reversible Non-flow Process Page
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    • Thermodynamic Relations
    • Property Changes for Change of State Page
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    • Partial Derivatives of U, G Page
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    • Internal Energy Change for Non-ideal Gas Page
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    • Isothermal Compression of Ideal Gas Page
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    • Isentropic Heating of Saturated Water Page
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    • Relation for Reversible Process Page
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    • Gibbs Free Energy Change for Phase Change Page
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    • Slope of Mollier Diagram at Constant Pressure Page
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    • Flow Processes
    • Superheated Vapor Page
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    • Throttling of Ideal Gas Page
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    • Enthalpy and Entropy Change for Expansion of Steam Page
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    • COP of Refrigeration Cycle Page
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    • Solution Thermodynamics
    • Fugacity at Low Pressure Page
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    • Partial Molar Enthalpy of Ideal Gas Mixture Page
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    • Molar Property of Solution Page
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    • Work for Separating a Mixture Page
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    • Phase Equilibrium
    • Degree of Freedom from Phase Rule Page
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    • Equilibrium Composition from Raoult's Law Page
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    • Boiling Point of Immiscible Liquid Mixture Page
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  • Assessments

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