Thermodynamics - Video Lectures
Topic outline
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Bubble Composition from P, T, Vapor Pressure Data Page1998-22-tdA mixture of \(A\) and \(B\) conforms closely to Raoult’s law. The pure component vapor pressures \(P_A^{\text {sat}}\) and \(P_B^{\text {sat}}\) in kPa are given by (\(T\) in \(^\circ \)C) \[ \begin {align*} \ln P_A^{\text {sat}} &= 14.27 - \frac {2945}{T + 224} \\
\ln P_B^{\text {sat}} &= 14.20 - \frac {2973}{T + 209} \end {align*} \] If the bubble point of a certain mixture of \(A\) and \(B\) is 76\(^\circ \)C at a total pressure of 80 kPa, find the mole fraction of \(A\) in the first vapor that forms.
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Pressure Range for Two-phase at Constant Temperature Page
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Excess Gibbs Free Energy from VLE Data Page
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VLE of Non-ideal Solution from Azeotropic Data Page
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VLE from Azeotropic Composition Page
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Henry's Law for Solute and Raoult's Law for Solvent Page
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