Quick Recap

The meeting covered various aspects of chemical reaction engineering, including material balance, stoichiometry, and reactor calculations. MSubbu discussed problem-solving methods, such as determining limiting reactants, calculating conversions, and analyzing flue gas compositions. The session also included information about upcoming tests, encouragement for active participation, and clarification on concepts like percentage excess in combustion reactions.

Next Steps

  • Students to take the tests for Process Calculations posted by Prof. Subbu.
  • Students to submit their test workouts as PDF or JPG files for verification.
  • Students to prepare for the upcoming thermodynamics topics on Basic Concepts and PVT behavior.
  • Prof. Subbu to post the problem list for Thursday's thermodynamics session by Wednesday morning.
  • Students to start studying thermodynamics topics from Wednesday after completing the Process Calculations tests.
  • Students to feel free to ask doubts or share views during discussion sessions to enhance learning.
  • Students to consider using voice messages on WhatsApp for explaining doubts to Prof. Subbu when needed.

SUMMARY

Addressing Past GATE Questions and Material Balance: In the meeting, MSubbu discussed the plan for the class, which included addressing a problem from the last session and covering material balance with reactions. He mentioned that the syllabus could not be covered in one hour and that he had prepared a good number of questions from past gate questions. MSubbu also asked about the usefulness of the previous session and acknowledged some network issues. He encouraged the team to take the test and mentioned that the questions were mostly from their Kevin R. and Stoichiometry book. MSubbu also mentioned that he would post the problem lists in the video lecture course and that the questions were linked to the process correlation, textual course. He then proceeded to discuss the problems, including getting the limiting reactant and the percentage of excess reactant, and the concept of degree of completion of reaction.

Wet Gas Composition Analysis: MSubbu discussed the composition of wet gas from dry gas data, focusing on the analysis of stack gas and the exclusion of water content. He explained the importance of mole fraction in determining the composition of the dry gas and the need to find the N2 content in the wet gas. MSubbu also discussed the humidity measurement and its role in determining the mole fraction of H2O in the stack gas. He then moved on to discuss the components of reactor exit for a given conversion, using the reaction stoichiometry and molar flow rate at the inlet. However, he noted a small mistake in the problem and decided to correct it later.

CO2 Content in Flue Gas: MSubbu discussed the maximum possible CO2 content in flue gas from methane combustion. He explained that the maximum CO2 content is achieved when stoichiometric air is supplied, resulting in minimal N2 and no excess O2. He also clarified that the dry flue gas will consist of CO2 and N2, with the CO2 content being 11.7%. MSubbu emphasized the importance of understanding the meaning of 'dry' in this context. He also discussed the possibility of excess oxygen in flue gas, explaining that it can be determined by analyzing the reactions of carbon and oxygen.

Solving Chemical Reaction Problems: The discussion focuses on solving a chemical reaction problem using different methods. MSubbu explains the extent of reaction method and the atomic balance method to calculate the reactants and products. He demonstrates that for one mole of carbon, one mole of oxygen is used in the reaction, resulting in no excess oxygen. Karthikeyan expresses that he finds the atomic balance method easier to understand, especially for complex problems. MSubbu encourages students to use whichever method they are comfortable with and mentions that the class is open for new students to join at any time, with adjusted charges for late joiners.

Degree of Completion in Reaction Mixtures: In the meeting, MSubbu discussed the concept of degree of completion in a reaction mixture. He explained that the degree of completion is based on the limiting reactant and is calculated as the percentage conversion of the limiting reactant. MSubbu also discussed the importance of identifying the limiting reactant and how it determines the degree of completion. He used an example of a reaction between CO and O2 to illustrate his points. Additionally, MSubbu touched upon the topic of percentage excess air from flue gas composition, explaining how to calculate it using the complete specification of the flue gas. He emphasized the importance of making atomic balances on carbon, oxygen, and hydrogen to arrive at the answer.

Chemical Reactions - Conversions and Recycling: The discussion covers various aspects of chemical reaction engineering, focusing on conversions and recycling in reactors. MSubbu explains how to calculate single-pass and overall conversions for different reactor setups. He demonstrates the calculation of percentage excess oxygen in a combustion reaction and shows how to determine mole fractions in reactor exit streams. The instructor also explains how to calculate recycle rates for given conversions and emphasizes the importance of representing problems schematically. He works through several example problems, including one involving carbon black production from methane, to illustrate these concepts. The session concludes with a comparison of single-pass and overall conversions in two different reactor scenarios.

Team Learning and Upcoming Test Preparation: In the meeting, MSubbu discussed the progress of the group's learning and the upcoming test. He emphasized the importance of utilizing the current limited group size and encouraged the team to finish their work. MSubbu also discussed the clarity of audio and video during the sessions, noting that there was no significant lag. He encouraged the team to participate more actively in the discussion sessions, sharing their knowledge and views to enhance their learning. The team was also reminded to prepare for the upcoming test.

Clarifying Percentage Excess in Combustion Reactions: The discussion focuses on clarifying the concept of percentage excess in combustion reactions. MSubbu explains that the percentage excess is always based on the complete combustion reaction, even if partial combustion occurs. For carbon, this means considering carbon going to carbon dioxide, regardless of any carbon monoxide formation. MSubbu emphasizes that this terminology is consistent for other elements like sulfur and hydrogen. The group also discusses an upcoming test on Process Calculations.

Last modified: Monday, 2 June 2025, 9:43 AM