MT-Class-5-Summary
10-July-2025
Extraction
Quick Recap
The meeting covered the current status of the classes and upcoming course content, including discussion of mass transfer topics and plans for fast-track classes with a focus on test questions. MSubbu explained key concepts in extraction processes, including ternary diagrams, selectivity, and phase behavior relationships between absorption. The session concluded with detailed explanations of solvent extraction principles, mass transfer calculations, and equations for absorption / stripping and extraction operations, including discussions of operating lines, equilibrium curves, and stage calculations.
Next Steps
- Students to spend at least 1-1.5 hours daily studying content on MSubbu's website.
- Students to take up tests posted on MSubbu's website regularly to assess their learning.
- Students to prepare for upcoming fast track classes starting in September.
- MSubbu to release mock exams from October onwards.
- MSubbu to start Chemical Reaction Engineering classes from coming Thursday.
- MSubbu to finish all subject (60% syllabus of GATE) instruction by August 14th.
- MSubbu to clarify on applicability of equations (Kremser and NTU formulas) for high concentration solutions.
SUMMARY
Course Completion and Exam Preparation
MSubbu discussed the current status of the classes and emphasized the importance of regular course content access. He announced the last topic of mass transfer, extraction, and outlined upcoming discussion sessions on distillation and mass transfer review. MSubbu shared plans for fast-track classes, including a new approach of focusing on test questions and reducing fundamental explanations. He encouraged students to spend time on his website for additional learning resources and set a target to finish the course by August 14th. MSubbu also mentioned upcoming mark exams and the goal of ranking within the top 50 students, contingent on student participation and effort.
Ternary Diagrams in Extraction Processes
MSubbu explained the concept of ternary diagrams and their application in extraction processes. He described how to read and interpret the compositions of mixtures, including the use of tie lines and equilibrium curves. MSubbu also discussed the concept of selectivity in extraction, comparing it to relative volatility in distillation. He explained how to calculate selectivity and emphasized the importance of understanding the phase behavior of mixtures in extraction processes.
Two-Phase System Lever Rule Demonstration
MSubbu explained the relationship between vapor and liquid phases in a two-phase system using a lever arm rule. He demonstrated how the ratio of raffinate to extract (R by E) is equivalent to the ratio of EM to RM, where \(x\) represents the dryness fraction. MSubbu also discussed how the amount of extract and raffinate can be calculated by multiplying the respective phases by their respective distances on a phase diagram. He emphasized the importance of understanding these relationships to better interpret steam tables and phase behavior.
Solvent Extraction and Solute-Free Coordinates
MSubbu explained the concepts of solvent extraction and solute-free coordinates, discussing the equilibrium data and mass balances for both cross-current and countercurrent operations. He emphasized the importance of using solute-free coordinates for easier calculations and highlighted the similarities between extraction and absorption/stripping processes. MSubbu also explained how to find the minimum solvent flow rate using equilibrium data and mass transfer principles.
Mass Transfer Calculations for Absorption
The discussion focused on mass transfer calculations and equations for absorption and extraction operations. MSubbu explained how to convert mass fractions to mass ratios and demonstrated calculations for operating lines and equilibrium curves. They discussed Kremser's equation for determining the number of stages in a multistage extraction process, using specific data for solvent flow rates and concentrations. The conversation also covered the calculation of NTU (Number of Transfer Units) for overall gas phase service, with emphasis on understanding the driving force and concentration changes across the transfer units.