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Theory
Checklist - Theory
Theory - Part 1
Basic Concepts - slides
PVT Behavior of Pure Components - slides
First Law - slides
Theory - Part 2
Second Law - slides
Thermodynamic Relations - slides
Theory - Part 3 - Flow Processes
Slides
Theory - Part 4 - Solution Thermodynamics
Slides
Theory - Part 5 - Phase Equilibria and Reaction Equilibria
Slides
Basic Concepts
CheckList - Basic Concepts
Questions - Basic Concepts
Mass of Piston for a given Pressure of Cylinder
Kinetic Energy Change of a Moving System
Work of Free Expansion
Work of Sudden Expansion
Representing Work in PV Diagram
Net Work from PV Diagram
Work of Constant Pressure Expansion of Air
Work Done in a Process with PV = Constant
Work Done in a Process with Linear Relation between P and V
Work done by a Gas against Constant Resisting Pressure
Work Done in a Sequence of Processes
Work in Melting of Ice
Processes in Piston-Cylinder System
Temperature Change of Ideal Gas due to Expansion
Change in Pressure for a Given Change in Temperature
Temperature of System for Movement of Piston
Heating of Tank Contents
Heating of a Gas Confined in a Piston-Cylinder Arrangement
New Temperature Scale
PVT Behavior
CheckList - PVT Behavior
Questions - PVT Behavior
Ideal Gas - Pressure Temperature Conditions
Conditions at Critical Point
Constant of Cubic Equation of State from Critical Point Data
Parameters of vander Waals Equation
Compressibility Factor at Critical Point
Solid to Vapor Transformation
Density of Ideal Gas
Temperature of Ideal Gas
Pressure of Ideal Gas Mixture
Pressure of Connected Reactors
Mass of Gas in a Pressure Vessel
Pressure from van der Waals Equation
Compressibility Factor
Compressibility Factor from Corresponding State Principle
Compressibility Factor of Water Vapor
Compressibility Factor from van der Waals Equation
Volume from Compressibility Factor
Density of Natural Gas from Compressibility Factor
Work for Isothermal Compression of Liquids
Volume from Virial Equation - Newton-Raphson Method
Mass of Vapor-Liquid Mixture
Heating of Two-phase Mixture in Rigid Tank
Heating of Liquid-Vapor Mixture in a Rigid Tank
First Law
CheckList - First Law
Questions - First Law
Heat Input at Constant Pressure
Heat Input at Constant Pressure - Another Explanation
Process with Heat Equal to Work
Process Giving Maximum Work for a Given Heat Input
PV Curve of Isothermal and Adiabatic Processes
Work of Adiabatic Process
Internal Energy Change of Ideal Gas from PV Curves
Enthalpy Change of Ideal Gas
Q, W, U of Processes
Work of Closed System
Relation for Heat Gain
Heat Transfer to Piston-Cylinder System
Internal Energy Change, Heat and Work Interactions of Cyclic Process
Thermodynamic Cycle
Heat Flow Estimation from PV Diagram
Sudden Expansion of Gas
Internal Energy Change of Ideal Gas
Specific Heat of Ideal Gas
Heat and Work Interactions of Closed System
Q of a Step in a Cyclic Process from PV Diagram
Energy Interactions of Closed System
Heat Transfer to a Closed System
Electrical Heating of Closed System
Heat and Work Interactions of a Cyclic Process
Heat Transfer of a Cycle from PV Diagram
Irreversible Compression
Ideal Gas - Conditions and Processes
Enthalpy Change of Steady Flow Process
Flow of Air for a Given Power Output of Turbine
Heat Transfer from Steady Flow Compressor
Work of Turbine
Work done by Turbine
Second Law
CheckList - Second Law
Questions - Second Law
Violation of Thermodynamic Laws
Thermodynamic Possibilities
Feasibility of Thermodynamic Cycle
Reversible Non-flow Process
Total Entropy Change for Heating of Water
Internal Energy and Entropy Changes for Cooling Process
Internal Energy and Entropy Changes of Heat Transfer
Reversible Heat Transfer
Entropy Change of Cyclic Process
Isothermal Expansion of Ideal Gas
Maximum Work of Heat Engine
Increasing the Efficiency of Carnot Cycle
Power from Unloading of LNG
Carnot Refrigerator Driven by Carnot Engine
Entropy Change of Ideal Gas
Entropy Change for Irreversible Compression of Ideal Gas
Entropy Change for Heat Transfer
Entropy Change for Mixing Hot and Cold Water
Entropy Change for Freezing Benzene with Ice-Water
Entropy Change for Mixing Water with Ice-Water Bath
Entropy of Two-phase Mixture
Maximum Amount of Work from a Heat Engine with a Finite Heat Source
Efficiency of a Thermodynamic Cycle
Equilibrium Temperature for Heat Exchange
Thermodynamic Cycle between Three Reservoirs
Thermodynamic Relations
Checklist - Thermodynamic Relations
Questions - Thermodynamic Relations
Relation for Reversible Process
Gibbs Free Energy Change for Phase Change
Slope of Mollier Diagram
Isentropic Heating of Saturated Water
Isothermal Compression of Ideal Gas
PV Diagram to TS Diagram for Ideal Gas
Internal Energy Change for Non-ideal Gas
Partial Derivatives of U, G
Property Changes for Change of State
Partial Derivatives of PVT
Slope of Solid-Liquid Coexistence Line
Latent Heat from Vapor Pressure Data
Isothermal Compression of Water
Enthalpy Change of Non-ideal Gas
Thermodynamic Property Changes for Non-ideal Gas
Specific Heat Variation with Volume
Change of Melting Point with Pressure
Thermodynamic Relations for Phase Change
Flow Processes
Checklist - Flow Processes
Questions - Flow Processes
Filling of Gas to a Tank
Filling a Tank with Air from a Flow Line
Superheated Vapor
Throttling of Ideal Gas
T and S Changes for Throttling of Ideal Gas
Enthalpy and Entropy Change for Expansion of Steam
Cyclic Relation for P-T-H
Joule-Thomson Coefficient of Non-ideal Gas
Power from a Turbine
Steam Turbine - Enthalpy of Steam at Exit
Work of Steady Flow Compression
Work of Steady Flow Process
Velocity of Air at the Exit of Nozzle
Exit Velocity of Steam from Nozzle
Vapor Compression Refrigeration
COP of Refrigeration Cycle
Solution Thermodynamics
CheckList - Solution Thermodynamics
Questions - Solution Thermodynamics
Quick Review of Theory
Entropy Change of Mixing of Ideal Gases
Entropy Change of Mixing of Ideal Solution
Work for Separating a Mixture
Molar Property of Solution
Partial Molar Enthalpy of Ideal Gas Mixture
Volumes of Individual Components for Mixture
Partial Molar Volume
Partial Molar Volume from Density
Volume Change of Mixing
Partial Molar Enthalpy at Infinite Dilution
Molar Properties of Solution from Tabular Data
Variation of Residual Gibbs Free Energy
Residual Enthalpy from Equation of State
Fugacity at Low Pressure
Fugacity of Gas from Virial Equation
Fugacity from G
G/RT of Solution
Activity Coefficient and Excess Gibbs Free Energy
Activity Coefficients from Expression of GE/RT
Slope of Activity Coefficient vs Composition Curve
Phase Equilibria
Checklist - Phase Equilibria
Questions - Phase Equilibria
Quick Review of Vapor-Liquid Equilibrium - Theory
Data from Txy Diagram of VLE
Equilibrium Composition from Raoult's Law
Degree of Freedom from Phase Rule
Bubble Composition from P, T, Vapor Pressure Data
Bubble Pressure and Dew Pressure Calculations
Maximum Pressure for Existence of Vapor Phase
Boiling Point of Immiscible Liquid Mixture
Flash Vaporization
Relation between Azeotrope and Activity Coefficients
Checking for Azeotrope from Tabular Data of VLE
Pressure Range for Two-phase at Constant Temperature
Activity Coefficients and Excess Gibbs Free Energy from VLE Data
Excess Gibbs Free Energy from VLE Data
Equilibrium Vapor Composition from Vapor Pressure and Activity Coefficients
Range of Pressures for Existence of Two Phase
VLE of Non-ideal Solution from Azeotropic Data
VLE from Azeotropic Composition
Henry's Law for Solute and Raoult's Law for Solvent
Vapor Pressures and Henry's Law Constants from Partial Pressure Relations
Methane and Water in Equilibrium - Raoult's and Henry's Laws
Activity Coefficient and Excess Gibbs Free Energy- Thermodynamic Consistency
Reaction Equilibria
Checklist - Reaction Equilibria
Questions - Reaction Equilibria
Quick Review - Theory
Equilibrium Constant and Composition
Extent of Reaction
Equilibrium Constant of Chemical Reactions
Conversion of Reversible Exothermic Reaction
Relation between Equilibrium Constant and Extent of Reaction
Mole Balance in Multiple Reaction System
Equilibrium Composition and Conversion
Gibbs Free Energy of Formation from Gibbs Free Energy Change of Reactions
Equilibrium Constant from Combination of Reactions
Equilibrium Constant from Heat of Formation and Gibbs Free Energy of Formation
Equilibrium Composition from Heat of Formation, Free Energy Change of Formation, Specific Heat Data
Feed Composition from Product Composition and Gibbs Free Energy Change of Reaction
Equilibrium Composition of Multiple Reaction Equilibria
Equilibrium Conversion of Ammonia
Conversion of Reaction in the Presence of Inerts
Equilibrium Composition with Non-ideal Solution
Maximum Possible Conversion of Gaseous Reaction - Non-ideal Gas
Conversion of Gas-Solid Reaction
Equilibrium Composition of Heterogeneous Reactions